Dr. Payam Payamyar

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Payam graduated in February 2015 and stayed with us as a postdoctoral fellow from March 2015 until October 2016.

Currently at:

Harvard University, Cambridge, MA, USA

Dr. Payam Payamyar
Dr. Payam Payamyar

Research Interests

Payam's PhD project is focused on characterization of covalent 2D Polymers. By making use of the uncorrugated surface of water, he prepares sheets that are laterally larger than 2D Polymers made within crystals. For doing so, he uses a photo-sensitive monomer with three-fold symmetry (M3) which is synthesized in the group (Fig. 1). Considering the amphiphilic nature of this molecule, it is possible to spread and compress few micrograms of it at the air/water interface in order to form an Archimedean pattern. This experiment is done on a Langmuir trough (Fig. 2). Shining light on the pre-organized pattern of the monomers results in a sheet-like polymer that can be transferred onto copper grids (Fig. 3). Payam uses various microscopy, spectroscopy and mechano-chemical analyses to evaluate the properties of the sheets and to understand different aspects of polymerization in two-dimensions.
His work is carried out in close contact with many dedicated collaborators and teachers whose help has immensely contributed to the progress of his research. A brief list of his collaborators includes the groups of Prof. Benjamin T. King, Prof. G. Wegner, Prof. Andreas Stemmer, Prof. Renato Zenobi, Prof. Joost VandeVondele, Prof. Paola Ceroni and Dr. Andreas Borgschulte.

Amphiphilic macrocycle (M3)
Figure 1: Amphiphilic macrocycle (M3) with 3-fold symmetry. Anthracene moieties serve as binding sites by the use of [4+4] cyclo-addition
Langmuir trough
Figure 2: Langmuir trough equipped with in-situ fluorescence spectroscopy set-up. We follow the reaction path by using the photo-reactive nature of anthracene within
SEM image
Figure 3: SEM image of the covalent monolayer synthesized on Langmuir trough after photo-irradiation of an ensemble of M3 monomers. The bright grids are made of copper and serve to hold the polymer sheet. While the film is hanging from the grids, the rolled, ruptured parts help as a source of contrast

Publications

Polydopamine Films from the Forgotten Air/Water Interface
Florian Ponzio, Payam Payamyar, Anne Schneider, Mathias Winterhalter, Jerome Bour, Frederic Addiego, Marie-Pierre Krafft, Joseph Hemmerle and Vincent Ball
The Journal of Physical Chemistry Letters, vol. 5: no. 19, pp. 3436-3440, Washington, DC: American Chemical Society, 2014.
Synthesis of a Covalent Monolayer Sheet by Photochemical Anthracene Dimerization at the Air/Water Interface and its Mechanical Characterization by AFM Indentation
Payam Payamyar, Khaled Kaja, Carlos Ruiz Vargas, Andreas Stemmer, Daniel J. Murray, Carey J. Johnson, Benjamin T. King, Florian Schiffmann, Joost VandeVondele, Alois Renn, Stephan Götzinger, Paola Ceroni, Andri Schütz, Lay-Theng Lee, Zhikun Zheng, Junji Sakamoto and A. Dieter Schlüter
Advanced Materials, vol. 26: no. 13, pp. 2052-2058, Weinheim: Wiley-VCH, 2014.
Atomic force microscopy of two-dimensional monomer and polymer films
Hannes Beyer, Carlos Ruiz-Vargas, Khaled Kaja, Payam Payamyar, Mary J. Kory, A. Dieter Schlüter and Andreas Stemmer
Poster presented at the International Symposium on Synthetic Two-Dimensional Polymers, Zürich, Switzerland, June 2-3, 2014.
Room Temperature Synthesis of a Covalent Monolayer Sheet at Air/Water Interface Using a Shape-Persistent Photoreactive Amphiphilic Monomer
Yougen Chen, Ming Li, Payam Payamyar, Zhikun Zheng, Junji Sakamoto and A. Dieter Schlüter
ACS Macro Letters, vol. 3: no. 2, pp. 153-158, American Chemical Society, 2014.
Gram-scale synthesis of two-dimensional polymer crystals and their structure analysis by X-ray diffraction
Max J. Kory, Michael Wörle, Thomas Weber, Payam Payamyar, Stan W. van de Poll, Julia Dshemuchadse, Nils Trapp and A. Dieter Schlüter
Nature Chemistry, vol. 6: no. 9, pp. 779-784, S.l.: Nature Publ. Group, 2014.
Square-Micrometer-Sized, Free-Standing Organometallic Sheets and Their Square-Centimeter-Sized Multilayers on Solid Substrates
Zhikun Zheng, Carlos S. Ruiz-Vargas, Thomas Bauer, Antonella Rossi, Payam Payamyar, Andri Schütz, Andreas Stemmer, Junji Sakamoto and A. Dieter Schlüter
Macromolecular Rapid Communications, vol. 34: no. 21, pp. 1670-1680, Weinheim: Wiley, 2013.
A Two-Dimensional Polymer from the Anthracene Dimer and Triptycene Motifs
Radha Bhola, Payam Payamyar, Daniel J. Murray, Bharat Kumar, Aaron J. Teator, Martin U. Schmidt, Sonja M. Hammer, Animesh Saha, Junji Sakamoto, A. Dieter Schlüter and Benjamin T. King
Journal of the American Chemical Society, vol. 135: no. 38, pp. 14134-14141, Washington, DC: American Chemical Society, 2013.
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